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The study evaluates four primary technology pathways for Germany's power sector decarbonisation by 2050: 'All Tech.' (inclusive of nuclear and CCS), 'No CCS', 'No Nucl.', and 'No Nucl. No CCS'. The 'All Tech.' scenario is identified as the most competitive, offering the lowest total system costs and electricity prices. The 'No Nucl. No CCS' scenario, which most closely represents current German policy, results in the highest costs, highest electricity price volatility, and greatest reliance on transmission and hydrogen infrastructure. The analysis emphasizes that nuclear power and Carbon Capture and Storage (CCS) significantly enhance economic competitiveness and system resilience. It also explores the role of long-duration energy storage (LDES), finding that 24-hour systems can facilitate solar expansion and reduce reliance on costly hydrogen-fuelled power plants.